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引用次数: 1

摘要

讨论了3-甲基戊烷玻璃中溶剂化电子光离产生的热电子的实验热化长度lth。当电子能量在初始值E0>1 eV到0.1-0.2 eV之间时,假设电子e-hot的能量损失主要是由于分子内振动的激发,能量损失为σE>kBT。结果表明,该模型与实验数据吻合较好。得到了亚振动电子的空间分布。
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Thermalization of low energy electrons in hydrocarbon matrices

The experimental thermalization lengths, lth, for hot electrons e-hot produced by photoionization of solvated electrons in 3-methylpentane glass are discussed. For electron energies ranging from the initial value E0>1 eV down to 0.1–0.2 eV, the electron e-hot is assumed to loss energy mainly due to excitation of intramolecular vibrations with energy losses σE>kBT. It is concluded that this model is in agreement with experimental data on lth. The spatial distribution of subvibrational electrons is obtained.

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