纤维素纤维增强聚羟基丁酸酯-共戊酸酯的热、力学和环境降解特性

A. M. C. Grisa, Tiago C. A. Colombo, A. J. Zattera, R. N. Brandalise
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引用次数: 0

摘要

近年来,生物可降解聚合物的发展取得了进展,主要是由于迫切需要减少聚合物材料在自然界中被不当丢弃时的影响。然而,与目前广泛使用的商品聚合物相比,这些材料的机械强度和成本等特性仍面临着重大挑战。在此目标的推动下,本研究的重点是开发一种由纤维素纤维增强的可生物降解聚合物聚(羟基丁酸酯-共戊酸酯)(PHBV)组成的复合材料,这种材料价格便宜且储量丰富。分析了不同纤维含量增强聚合物的力学性能和热性能,并与纯材料进行了比较。此外,还进行了埋土试验,以评价所研究的组合物的环境降解特性。结果表明,将纤维素纤维掺入可生物降解基质中,既能优化使用过程中的力学性能,又能在使用后加速高分子材料的环境降解,且处理得当,表明可生物降解复合材料具有环保性。
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Thermal, mechanical and environmental degradation characteristics of polyhydroxybutyrate-co-valerate reinforced with cellulose fibers
The development of biodegradable polymers has advanced in recent years, mainly due to the overwhelming need to reduce the impact of polymeric materials when improperly discarded in nature. However, there are major challenges to be surpassed, especially regarding characteristics such as mechanical strength and cost of such materials, when compared to commodity polymers widely used today. Motivated by this goal, this study focused on the development of a composite material consisting of a biodegradable polymer the poly(hydroxybutyrate-co-valerate) (PHBV) reinforced with cellulose fibers, which are cheap and abundant. Mechanical and thermal properties of the polymer reinforced with different fiber contents were analyzed and compared with the neat material. Also, a burial- soil test was carried out to evaluate the environmentally degradable characteristics of the compositions studied. Results showed that the incorporation of cellulose fibers into the biodegradable matrix can both optimize the mechanical properties in use, and accelerating the environmental degradation of the polymeric material after use, when properly disposed, showing that biodegradable composites are environmentally friendly.
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