金属-有机骨架纳米片气体分离在混合基质膜中诱导聚合物结晶度

IF 4.9 Q1 ENGINEERING, CHEMICAL Journal of Membrane Science Letters Pub Date : 2022-05-01 DOI:10.1016/j.memlet.2022.100017
Dechao Wang , Yunpan Ying , Yaping Zheng , Yunchuan Pu , Ziqi Yang , Dan Zhao
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引用次数: 5

摘要

研究了一类新型二维(2D)金属-有机骨架纳米片NUS-8-COOH在混合基质膜(MMMs)中对固有微孔(PIM-1)基质聚合物的诱导结晶度行为。由NUS-8-COOH纳米片诱导的增强结晶度的理想可以扩展到其他类型的含二维纳米片的mm,从而为构建具有优异界面相容性的mm提供了丰富的机会,从而增强了气体分离性能。
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Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation

The induced crystallinity behavior of the polymer of intrinsic microporosity (PIM-1) matrix in mixed matrix membranes (MMMs) by a novel class of two-dimensional (2D) metal-organic framework nanosheets, i.e., NUS-8-COOH, is demonstrated. The proposed ideal of enhanced crystallinity induced by NUS-8-COOH nanosheets can be extended to other classes of 2D nanosheet-containing MMMs, thus opening up plentiful opportunities for constructing MMMs with superior interfacial compatibility toward enhanced gas separation performance.

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