球团法制备Sr2Si5N8: Eu2+红色荧光粉及其光学特性

Yu-Bing Lan, Dong Wang, Dongliang Xie, Jun Tan, Bowen Li, Mei Zhang, Yan Chen
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引用次数: 4

摘要

采用球团法成功合成了性能优良的红色Sr2Si5N8: Eu2+荧光粉,是一种有效的合成技术。详细研究了球团压力、样品在碳粉中的位置、Eu2+离子浓度等反应条件对Sr2Si5N8: Eu2+荧光粉结晶度、粒径及光致发光性能的影响。结果表明,最佳制备条件为1500,球团压力为5 MPa,中间位置为碳粉。该荧光粉在近紫外和蓝光led的激发下提高了效率,并在620nm左右发出红光。此外,当Eu2+离子的摩尔浓度达到0.001时,Sr2Si5N8: Eu2+荧光粉与uv芯片结合成功制备出发光效率最高的红色led,发光效率为9.443 lm/W。
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Preparation of Red Phosphor Sr2Si5N8: Eu2+ by Pellet Method and Its Optical Characteristics
Red Sr2Si5N8: Eu2+ phosphor with excellent properties was successfully synthesized by pellet method, an effective synthesis technology presented in this work. The influence of reactive conditions such as pellet pressure, position of samples in carbon powder, and Eu2+ ion concentration on the properties of crystallinity, particle size, and the photoluminescence properties of Sr2Si5N8: Eu2+ phosphor were studied in detail. Our results show that the optimum preparation condition is 1500, 5 MPa pellet pressure, and the middle position in carbon powder. The phosphor has improved its efficiency under excitation of near UV and blue LEDs, and it emits red light at around 620 nm. In addition, red LEDs were successfully prepared by using Sr2Si5N8: Eu2+ phosphor combined with UV-chips with maximum luminous efficiency at 9.443 lm/W, when the molar concentration of Eu2+ ion reached 0.001.
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