{"title":"A2CuCl4,2H2O (A = NH4, K，或Rb)单晶的远红外反射光谱:畸变八面体水氯酸盐(II)阴离子的铜-氯振动","authors":"J. Dunsmuir, A. Lane","doi":"10.1039/J19710002724","DOIUrl":null,"url":null,"abstract":"The polarised far-i.r. reflectance spectra of A2CuCl4,2H2O (A = NH4, K, or Rb) single crystals have been recorded in the region 40–400 cm–1. These have permitted the observation and assignment of most of the predicted bands, including one at ca. 180 cm–1 due predominantly to the ‘long’ Cu–Cl stretching mode. Anomalies in the reflectance spectra of (111) faces of these crystals are discussed.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Far-infrared reflectance spectra of A2CuCl4,2H2O (A = NH4, K, or Rb) single crystals: copper–chlorine vibrations of the distorted octahedral aquochlorocuprate(II) anion\",\"authors\":\"J. Dunsmuir, A. Lane\",\"doi\":\"10.1039/J19710002724\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The polarised far-i.r. reflectance spectra of A2CuCl4,2H2O (A = NH4, K, or Rb) single crystals have been recorded in the region 40–400 cm–1. These have permitted the observation and assignment of most of the predicted bands, including one at ca. 180 cm–1 due predominantly to the ‘long’ Cu–Cl stretching mode. Anomalies in the reflectance spectra of (111) faces of these crystals are discussed.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710002724\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002724","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
摘要
偏振的远红外线。A2CuCl4,2H2O (A = NH4, K，或Rb)单晶的反射光谱在40-400 cm-1范围内。这使得大多数预测波段的观测和分配成为可能，包括一个大约180 cm-1的波段，主要是由于“长”Cu-Cl拉伸模式。讨论了这些晶体(111)面反射光谱中的异常现象。
Far-infrared reflectance spectra of A2CuCl4,2H2O (A = NH4, K, or Rb) single crystals: copper–chlorine vibrations of the distorted octahedral aquochlorocuprate(II) anion
The polarised far-i.r. reflectance spectra of A2CuCl4,2H2O (A = NH4, K, or Rb) single crystals have been recorded in the region 40–400 cm–1. These have permitted the observation and assignment of most of the predicted bands, including one at ca. 180 cm–1 due predominantly to the ‘long’ Cu–Cl stretching mode. Anomalies in the reflectance spectra of (111) faces of these crystals are discussed.
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