Revathi B. K. , Reuben Jonathan D. , Sathya S. , Krishna Priya M. , Anish Fathima A. , Yuvashri R. , Usha G.
{"title":"新型非线性光学材料：(4-氯苯基)(4-羟基哌啶-1-基)甲酮的合成与表征","authors":"Revathi B. K. , Reuben Jonathan D. , Sathya S. , Krishna Priya M. , Anish Fathima A. , Yuvashri R. , Usha G.","doi":"10.1080/10406638.2023.2232510","DOIUrl":null,"url":null,"abstract":"<div><p>A new organic and nonlinear optical material namely (4-chlorophenyl) (4-hydroxypiperidin-1-yl) methanone [HPCP] was synthesized from the mixture of 4-hydroxypiperidiene, triethylamine, and 4-chlorobenzoyl chloride by solution growth technique. The 3D structure of the title crystal has been derived using the X-ray diffraction (XRD) spectrum. The compound was crystallized in the orthorhombic crystal system with non-centrosymmetric space group Pca2<sub>1</sub>. Optical properties of the as-grown compound have been elucidated through <sup>1</sup>H-NMR, UV-Visible, FTIR, and PL spectral studies. The melting point, stages of mass decay, and thermal stability of the synthesized material were obtained by TG/DTA thermal analysis. Vickers microhardness test was performed to comprehend its mechanical strength. The second harmonic generation (SHG) efficiency was estimated by employing Q-switched high energy, Nd: YAG the laser source, and the SHG efficiency was found to be 1.73 times that of KDP, the reference crystal.</p></div>","PeriodicalId":20303,"journal":{"name":"Polycyclic Aromatic Compounds","volume":null,"pages":null},"PeriodicalIF":2.4000,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of a New Non-Linear Optical Material: (4-Chlorophenyl)(4-Hydroxypiperidin-1-yl) Methanone\",\"authors\":\"Revathi B. K. , Reuben Jonathan D. , Sathya S. , Krishna Priya M. , Anish Fathima A. , Yuvashri R. , Usha G.\",\"doi\":\"10.1080/10406638.2023.2232510\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A new organic and nonlinear optical material namely (4-chlorophenyl) (4-hydroxypiperidin-1-yl) methanone [HPCP] was synthesized from the mixture of 4-hydroxypiperidiene, triethylamine, and 4-chlorobenzoyl chloride by solution growth technique. The 3D structure of the title crystal has been derived using the X-ray diffraction (XRD) spectrum. The compound was crystallized in the orthorhombic crystal system with non-centrosymmetric space group Pca2<sub>1</sub>. Optical properties of the as-grown compound have been elucidated through <sup>1</sup>H-NMR, UV-Visible, FTIR, and PL spectral studies. The melting point, stages of mass decay, and thermal stability of the synthesized material were obtained by TG/DTA thermal analysis. Vickers microhardness test was performed to comprehend its mechanical strength. The second harmonic generation (SHG) efficiency was estimated by employing Q-switched high energy, Nd: YAG the laser source, and the SHG efficiency was found to be 1.73 times that of KDP, the reference crystal.</p></div>\",\"PeriodicalId\":20303,\"journal\":{\"name\":\"Polycyclic Aromatic Compounds\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2024-05-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polycyclic Aromatic Compounds\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1040663823016639\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polycyclic Aromatic Compounds","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1040663823016639","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Synthesis and Characterization of a New Non-Linear Optical Material: (4-Chlorophenyl)(4-Hydroxypiperidin-1-yl) Methanone
A new organic and nonlinear optical material namely (4-chlorophenyl) (4-hydroxypiperidin-1-yl) methanone [HPCP] was synthesized from the mixture of 4-hydroxypiperidiene, triethylamine, and 4-chlorobenzoyl chloride by solution growth technique. The 3D structure of the title crystal has been derived using the X-ray diffraction (XRD) spectrum. The compound was crystallized in the orthorhombic crystal system with non-centrosymmetric space group Pca21. Optical properties of the as-grown compound have been elucidated through 1H-NMR, UV-Visible, FTIR, and PL spectral studies. The melting point, stages of mass decay, and thermal stability of the synthesized material were obtained by TG/DTA thermal analysis. Vickers microhardness test was performed to comprehend its mechanical strength. The second harmonic generation (SHG) efficiency was estimated by employing Q-switched high energy, Nd: YAG the laser source, and the SHG efficiency was found to be 1.73 times that of KDP, the reference crystal.
期刊介绍：
The purpose of Polycyclic Aromatic Compounds is to provide an international and interdisciplinary forum for all aspects of research related to polycyclic aromatic compounds (PAC). Topics range from fundamental research in chemistry (including synthetic and theoretical chemistry) and physics (including astrophysics), as well as thermodynamics, spectroscopy, analytical methods, and biology to applied studies in environmental science, biochemistry, toxicology, and industry. Polycyclic Aromatic Compounds has an outstanding Editorial Board and offers a rapid and efficient peer review process, as well as a flexible open access policy.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
