{"title":"TiO2上铑负载离子液体催化剂催化乙烯制丙醇","authors":"Lam Vu Tung, Hung Trinh Ba, T. Le Minh","doi":"10.51316/jca.2022.058","DOIUrl":null,"url":null,"abstract":"Rhodium catalyst systems for hydroformylation has been researched widely in the literature. Using ionic liquid for rhodium-supported catalyst facilitates this reaction. In this work, TiO2 support was first time used. From the FT-IR, EPR, and surface area analysis, the components of supported ionic liquid phase can be seen after the impregnation of ionic liquid into the support’s porous structure. The main product for the ethylene conversion is propan-2-ol, as a subsequent hydrogenation product after hydroformylation. Pressure and temperature difference are evaluated to understand the influence on selectivity and product formation.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"11 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rh-supported ionic-liquid catalysts on TiO2 for the conversion of Ethylene to propanol\",\"authors\":\"Lam Vu Tung, Hung Trinh Ba, T. Le Minh\",\"doi\":\"10.51316/jca.2022.058\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Rhodium catalyst systems for hydroformylation has been researched widely in the literature. Using ionic liquid for rhodium-supported catalyst facilitates this reaction. In this work, TiO2 support was first time used. From the FT-IR, EPR, and surface area analysis, the components of supported ionic liquid phase can be seen after the impregnation of ionic liquid into the support’s porous structure. The main product for the ethylene conversion is propan-2-ol, as a subsequent hydrogenation product after hydroformylation. Pressure and temperature difference are evaluated to understand the influence on selectivity and product formation.\",\"PeriodicalId\":23507,\"journal\":{\"name\":\"Vietnam Journal of Catalysis and Adsorption\",\"volume\":\"11 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-10-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Vietnam Journal of Catalysis and Adsorption\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.51316/jca.2022.058\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vietnam Journal of Catalysis and Adsorption","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.51316/jca.2022.058","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Rh-supported ionic-liquid catalysts on TiO2 for the conversion of Ethylene to propanol
Rhodium catalyst systems for hydroformylation has been researched widely in the literature. Using ionic liquid for rhodium-supported catalyst facilitates this reaction. In this work, TiO2 support was first time used. From the FT-IR, EPR, and surface area analysis, the components of supported ionic liquid phase can be seen after the impregnation of ionic liquid into the support’s porous structure. The main product for the ethylene conversion is propan-2-ol, as a subsequent hydrogenation product after hydroformylation. Pressure and temperature difference are evaluated to understand the influence on selectivity and product formation.
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