普通手性金属配合物不适合做超材料吗?

Sato Yoshiyuki, Nakane Daisuke, Akitsu Takashiro
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引用次数: 0

摘要

在典型的超材料中,我们在这篇手性光超材料微综述中重点讨论了光的“功能”和手性“元素”。作者对无机材料,特别是过渡金属配合物感兴趣。金属配合物是一种长期以来因其光学性质(光吸收)和手性(旋向光谱、结构晶体化学和不对称催化反应)而被研究的化合物。然而,由于单位是一个“分子”,迄今为止很少有(光学)超材料的例子被报道。是否有可能使用一种方法添加功能作为复合材料?不,由纳米图案产生的功能是很难改造的。有没有一种方法可以将无机和有机之间的丰富化合物与最先进的光学超材料融合在一起?
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Are Commonplace Chiral Metal Complexes Unsuitable for Metamaterials?
Among typical metamaterials, we focus on the light "function" and chiral "element" in this chiral light metamaterial minireview. The authors are interested in inorganic materials, especially transition metal complexes. Metal complexes are compounds that have been studied for a long time for their optical properties (light absorption) and chirality (chiroptical spectroscopy, structural crystal chemistry, and asymmetric catalytic reactions). However, since the unit is a "molecule", few examples as (optical) metamaterials have been reported to date. Is it possible to add a function as a composite material using one method? No, the functions resulting from the nano pattern are very difficult to retrofit. Is there a way to fuse the rich compounds at the boundary between inorganic and organic with state-of-the-art optical metamaterials?
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