片状云母的热行为

Stanley Ruthberg
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引用次数: 0

摘要

在高达 600 °C 的温度下,对三种光谱类型的麝香石片云母(即极粉红红宝石、浅绿和深绿)进行了热处理。在研究颜色的同时,还研究了视轴角和吸收光谱(0.3 至 15 μ)的变化。根据这些光谱类型对白云母片进行的区分扩展到了表观视轴角的行为以及热处理时光谱的某些区域。粉红色的相关吸收区域(0.47 至 0.6 μ)可以通过适当的热处理得到增强或漂白,但 3 至 3.5 μ 的相关红外多倍光谱几乎不受影响。12 μ 处的吸收带强度随处理温度的升高而增加。人们怀疑 0.47 至 0.6 μ 的吸收带是色心的结果。
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Thermal Behavior of Muscovite Sheet Mica.

The three spectral types of muscovite sheet mica, i.e., very pink ruby, light green, and dark green, were subjected to heat treatments at temperatures up to 600 °C. The changes in the apparent optic axial angle and in the absorption spectra (0.3 to 15 μ) were studied along with color. The differentiation of muscovite sheet according to these spectral types extends to the behavior of apparent optic axial angle and to certain regions of the spectrum under heat treatment. The pink associated absorption region (0.47 to 0.6 μ) can be enhanced or bleached away by appropriate thermal treatment, although the associated infrared multiplet at 3 to 3.5 μ is little affected. The absorption band at 12 μ increases in intensity with temperature of treatment. It is suspected that the 0.47 to 0.6 μ absorption is the result of color centers.

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