新型高效减水剂和引气剂的化学结构与性能

M. Shonaka, K. Kitagawa, H. Satoh, T. lzumi, T. Mizunuma
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引用次数: 13

摘要

高范围减水剂(高效减水剂),一般是通过电磁力吸附水泥颗粒表面,使颗粒分散。近年来,以长链聚乙烯氧化物(EO)为分支的新型高范围减水剂得到了发展。当新分子吸附在颗粒上时,可以认为长EO链在水/水泥混合物中膨胀,并且每个颗粒由于它们的空间排斥力而不是电分散。因此,它能给混凝土配合比带来良好的和易性,并能在较长时间内保持流动性,而不会在凝结时产生阻滞。因此,它可以适用于各种混凝土,如高、超高强度混凝土。
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Chemical Structures and Performance of New High-Range Water-Reducing and Air-Entraining Agents
High range water reducing agents (superplasticizers), in general, adsorb the surface of cement particles and disperse the particles by means of electric force. Recently, there has been a development of a new type of high range water reducing agents which have characteristically long chains of polyethylene oxides (EO) as branches. When the new molecules adsorb on the particles, it is considered that long EO chains are expanded in the water/cement mixture and that each particle disperse due to their steric repulsion instead of electric. So, it can bring good workability to the concrete mix and retain fluidity for a longer period without retarding on the setting. Therefore, it can be applied to various concrete, such as high and ultra high strength concrete.
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