用天然浮石粉部分替代二氧化硅以增强电子束辐照固化丁腈橡胶的机械和热性能

K. El‐Nemr, H. Radi, R. H. Helal
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引用次数: 1

摘要

目的浮石粉是聚合物工业中可用作补强填料的低成本矿物之一。浮石是一种高度多孔的火山玻璃,形成于爆炸性喷发。这种浮石因其具有各种极性基团的大表面积和易于加工而受到极大的关注。设计/方法/方法本研究旨在研究用天然浮石粉末部分替代二氧化硅(作为传统填料)对改善电子束辐射(剂量为25至150 kGy)固化丁腈橡胶的热性能和机械性能的影响。结果表明,在较低剂量下(浓度为5phr时),浮石粉的加入可提高材料的抗拉强度,最高可达75 kGy。此外,浮石粉的加入改善了热稳定性。原创性/价值灰石粉为火山基氧化铝和二氧化硅,主要成分为SiO2。它具有多孔结构,这是由熔岩在冷却过程中穿过空气时沉淀的溶解气体形成的。由于其多孔结构,具有低密度和高绝热性。它还具有耐高温和耐化学性,因此它成为塑料和橡胶工业中用作填料的首选材料。
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Partial replacement of silica by naturally occurring pumice powder for enhancing mechanical and thermal properties of nitrile rubber cured by electron beam irradiation
Purpose One of the low-cost minerals that can be used as reinforcing filler in polymer industry is pumice powder. Pumice is a highly porous volcanic glass formed during explosive eruptions. This pumice has received significant interest because of its large surface area with various polar groups and can be processed easily. Design/methodology/approach This study is carried out to investigate the effect of partial replacement of silica (as traditional filler) by naturally occurring pumice powder to improve the thermal and mechanical properties of nitrile butadiene rubber cured with electron beam radiation (doses from 25 to 150 kGy). Findings The results indicated that the addition of pumice powder increase the tensile strength at lower doses up to 75 kGy (especially at concentration of 5 phr). Besides, an improvement in the thermal stability was attained with the addition of pumice powder. Originality/value Pumice powder is volcanic-based alumina and silica which is mainly composed of SiO2. It has porous structure which is formed by dissolved gases precipitated during the cooling as the lava hurtles through air. Due to its porous structure, it has low density and high thermal insulation. It also has high temperature and chemical resistance, for these reasons it became preferable material to be used as filler in the plastic and rubber industry.
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