{"title":"硅烷和锗衍生物的振动谱。第五部分:二卤基(甲基)日耳曼的红外光谱和拉曼光谱","authors":"G. K. Barker, J. Drake, R. Hemmings, B. Rapp","doi":"10.1039/J19710003291","DOIUrl":null,"url":null,"abstract":"The i.r. and Raman spectra of the series of dihalogeno(methyl)germanes, MeGeHX2(X = F, Cl, Br, I) and their specifically deuteriated analogues, MeGeDX2, are recorded. A normal co-ordinate treatment based on a modified valence force field confirms the assignment of 17 of the 18 fundamental frequencies for each molecule. The torsional mode is not observed. The transferability of the force constants between the protonated and deuteriated species is tested.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The vibrational spectra of silane and germane derivatives. Part V. The infrared and Raman spectra of dihalogeno(methyl)germanes\",\"authors\":\"G. K. Barker, J. Drake, R. Hemmings, B. Rapp\",\"doi\":\"10.1039/J19710003291\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The i.r. and Raman spectra of the series of dihalogeno(methyl)germanes, MeGeHX2(X = F, Cl, Br, I) and their specifically deuteriated analogues, MeGeDX2, are recorded. A normal co-ordinate treatment based on a modified valence force field confirms the assignment of 17 of the 18 fundamental frequencies for each molecule. The torsional mode is not observed. The transferability of the force constants between the protonated and deuteriated species is tested.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710003291\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710003291","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The vibrational spectra of silane and germane derivatives. Part V. The infrared and Raman spectra of dihalogeno(methyl)germanes
The i.r. and Raman spectra of the series of dihalogeno(methyl)germanes, MeGeHX2(X = F, Cl, Br, I) and their specifically deuteriated analogues, MeGeDX2, are recorded. A normal co-ordinate treatment based on a modified valence force field confirms the assignment of 17 of the 18 fundamental frequencies for each molecule. The torsional mode is not observed. The transferability of the force constants between the protonated and deuteriated species is tested.
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