Y对原位合成TiB和TiC增强激光熔覆层显微组织的影响

J. Li, H. Wang
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引用次数: 0

摘要

采用激光熔覆的方法在Ti6Al4V表面制备了原位合成TiB和TiC颗粒增强钛基复合涂层。采用x射线衍射(XRD)、光学显微镜(OM)、扫描电镜(SEM)和电子探针微观分析(EPMA)等手段研究稀土Y对涂层微观结构的影响。结果表明:含Y涂层主要由大量α-Ti胞状枝晶和少量粗/细针状TiB、等轴TiC和球形Y2O3颗粒组成;在涂层中加入少量的Y (1-3 wt.%)可以细化组织,改善组织均匀性,增加共晶体的体积分数,使涂层具有更高的强度、显微硬度和韧性等优异的力学性能。当Y的添加量在2 ~ 3 wt.%范围内变化时,涂层的显微组织没有明显变化,只是共晶的体积分数逐渐增加。
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Effect of Y on microstructure of laser clad coatings reinforced by in situ synthesized TiB and TiC
Titanium-based composite coatings reinforced by in situ synthesized TiB and TiC particles were fabricated on Ti6Al4V by laser cladding. The effect of rare earth Y addition on microstructure of the coatings was investigated by means of X-ray Diffraction (XRD), Optical Microscope (OM), Scanning Electron Microscopy (SEM) and Electron Probe Micro-Analysis (EPMA). The results show that the coatings with Y mainly consist of a great amount of α-Ti cellular dendrites and few coarse/fine needle-shaped TiB, equiaxial TiC and spherical Y2O3 particles. A small amount of Y (1–3 wt.%) added to the coatings can refine the microstructure, improve the microstructural uniformity and increase the volume fraction of eutectics, which will endow the coatings with more excellent mechanical properties, such as higher strength, microhardness and toughness. When the addition content of Y varies from 2 wt.% to 3 wt.%, the microstructure of the coatings presents no significant difference except that the volume fraction of eutectics is increased gradually.
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