烷基-甲基萘磺酸盐表面活性剂的合成及表面活性研究

Zhongkui Zhao, Yan Ba, Zongshi Li, W. Qiao
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引用次数: 4

摘要

合成了一系列甲基萘磺酸烷基酯表面活性剂(AMNS),并通过红外光谱(IR)、紫外光谱(UV)和ESI-MS对其结构进行了表征。表面张力测量采用环法进行。研究了烷基侧链对临界胶束浓度(cmc)和c20表面张力(γ cmc)的影响。结果表明,所制备的阴离子表面活性剂具有良好的表面活性。在水溶液表面的吸附和表面活性剂胶束的热力学研究表明,烷基侧链和芳香环都归因于表面活性。
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Synthesis and Surface Activity of Alkyl-Methylnaphthalene Sulfonate Surfactants
A series of alkyl methylnaphthalene sulfonate surfactants (AMNS) were synthesized and their structures were confirmed by IR, UV and ESI-MS. The surface tension measurements were performed by the ring method. The effects of the alkyl side chains on critical micelle concentrations (cmc), and the surface tensions (γ cmc ) at cmc and C 20 were investigated. The results indicated that the anionic surfactants prepared exhibited good surface activity. The study of adsorption at the surfaces of aqueous solution and the thermodynamics of the surfactant micelles showed that both the alkyl side chains and the aromatic rings were attributed to the surface activity.
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