电池在未来能源学中的作用

S. Mentus
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摘要

自上世纪70年代初第一次石油危机以来,电化学家们一直在努力开发一种化学能源,以取代交通中的液体化石燃料。1980-1990年十年取得了显著的成功。由于一种新型材料——插层化合物,一种被称为锂离子电池的新型电池被商业化了,它的能量密度比以前的电池高得多。在这项工作中,解释了其高能量密度的起源。新型电池的出现有效地支持了便携式电子产品的使用和发展——移动电话、笔记本电脑、平板电脑等。从2010年开始,与全球防止气候变化的意图联系在一起,电池被赋予了电动汽车能源的角色。近年来,随着可再生能源使用强度的不断增加,电池也承担了电网储能的角色,具有平滑电网电压扰动的功能。所有这些都导致了电池使用量的大幅增加,并对电池生产所需的锂、钴和镍的全球资源供应提出了疑问。最近的预测是,这些资源将在2030-2040年的十年内很快耗尽。因此,迫切需要寻找新的电池类型,以维持(至少部分地)可用的锂资源,以满足更苛刻的应用。作为具有现实前景的解决方案的一部分,钠离子电池的发展目前正在进行中。在这个意义上,一些前景的阳极和阴极材料的考虑。
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THE ROLE OF BATTERIES IN NEAR-FUTURE ENERGETICS
Since the first oil crisis in early 70-ties, the electrochemists strive to develop a chemical power source able to replace the liquid fossil fuels in traffic. Noticeable success was achieved in the decade 1980-1990. Thanks to a new class of materials – intercalate compounds, a new battery called lithium-ion battery was commercialized, having much higher energy density than its predecessors. In this work the origin of its high energy density is explained. The emergence of new battery supported effectively the expansion of use and the development of portable electronics - mobile phones, lap-top calculators tablets etc. Since 2010, connected to the global intentions to prevent climate changes, the batteries received the role of the energy sources of electric cars. Recently, connected to the rising use of renewable energy sources known to suffer of changeable intensity, batteries take also the role of grid energy storage, having the function to smooth the disturbances in grid voltage. All this caused huge rise in batteries usage, and poses the question about the availability of global resources of lithium, cobalt and nickel needed for battery production. The recent forecast is that these resources will be exhausted very soon in the decade 2030-2040. Thus, there is a strong need to search for new battery types, to maintain, at least partly, available lithium resources for more demanding applications. As a part of solutions having real perspective, the development of sodium-ion battery is currently in progress. In that sense, some perspective anode and cathode materials were considered.
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