新型杂环双核席夫碱配合物的模板合成、表征及热表征

Synthesis and Reactivity in Inorganic and Metal-organic Chemistry Pub Date : 2004-11-01 DOI:10.1081/SIM-200026585

M. Sönmez, M. Şekerci

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引用次数: 8

摘要

摘要1‐氨基‐5‐苯甲酰‐4‐苯基‐1H‐嘧啶‐2‐1 (L’h2)在正丁醇中与苄基(L″O2)和Cu(AcO)2·H2O、NiCl2·6H2O、Co(AcO)2·4H2O、CdCl2·2H2O等盐以2:1:2的摩尔比反应，得到几种固体配合物[(M)2(L’)2(L″)(X)4]·nH2O。通过元素分析、摩尔电导、红外光谱、电子和热研究对希夫碱的前驱体和金属配合物进行了表征。

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The Template Synthesis, Characterization, and Thermal Investigation of New Heterocyclic Binucleating Schiff Base Complexes

Abstract 1‐Amino‐5‐benzoyl‐4‐phenyl‐1H‐pyrimidine‐2‐one (L′H2) reacts with benzil (L″O2) and salts Cu(AcO)2 · H2O, NiCl2 · 6H2O, Co(AcO)2 · 4H2O, CdCl2 · 2H2O in 2:1:2 molar ratio in n‐butanol to give several solid complexes of the general composition [(M)2(L′)2(L″)(X)4] · nH2O. The precursor and the metal complexes of the Schiff base have been characterized by elemental analyses, molar conductances, IR spectra, electronic, and thermal studies.

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Synthesis and Reactivity in Inorganic and Metal-organic Chemistry

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