新型合成水性粘合剂在三种固定模式下色浆印花棉织物中的应用

K. Haggag, M. El-Molla, N. O. Shake, N. Alian, F. El-Shall
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引用次数: 10

摘要

利用合成的水性聚氨酯丙烯酸酯(无挥发性有机化合物排放)粘结剂1-7,在棉织物上采用丝印技术进行颜料印花。经UV固化的粘结剂的FT-IR光谱显示,固化后的光谱图中ast C=C和δ: =C- h吸收带消失,证明通过末端自由丙烯酸晚期双键发生了交叉林金反应。印花织物的颜色强度取决于粘合剂的种类和浓度以及固定温度。在较低的固定温度下,在印花浆料中使用所制备的粘合剂,其K/S值优于在相同条件下使用浆料(包括商业粘合剂)印花织物的K/S值(节能省钱)。印刷样品的牢度性能取决于所用粘合剂的类型。所有印花样品的洗涤和排汗效果从好到好不等。随着脂肪族聚氨酯丙烯酸酯粘结剂浓度的增加,印花棉织物的K/S值略有提高。在棉颜料印花浆料中加入浓度为1%的聚氨酯丙烯酸酯(1-7),紫外固化或微波固化3 min为最佳工艺条件。与传统的热铜环技术相比,使用合成的聚氨酯丙烯酸酯粘合剂在印刷浆料和UV固化中获得的所有印刷样品的摩擦牢度结果都有所提高。结果表明,该结合剂可安全用于色织棉印花浆料的制备。
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Use of the Novel Synthesized Aqueous Binders for Pigment Printing Cotton Fabrics Using Three Modes of Fixation
Use of the synthesized aqueous polyurethane acrylate (no volatile organic compound emission) binders 1-7, in pigment printing of cotton fabrics using silk screen technique. FT-IR spectra of binders via UV curing show the disappearance of ast C=C and δ: =C-H absorption bands from the spectra chart of cured, which proofed the occurrence of cross lin king reaction via terminal free acry late double bond. Co lor strength of printed fabrics depends on binders' type and concentration as well as the fixat ion temperature. The K/S values at lo wer fixat ion temperatures on using the prepared binders in the printing paste are better than the K/S of fabric printed with paste including the commercial binder at the same condition ( saving energy& money). The fastness properties of the printed samples depend on the type of binder used. The washing and perspiration ranged fro m good to excellent for all printed samp les. Slightly enhancement in K/S values of printed cotton fabric with increase the concentration of aliphatic polyurethane acrylate binders was noticed. The presence of 1% concentration of polyurethane acrylate binders (1-7) in the cotton pigment printing paste, and either UV curing or microwave cured for 3 min. could be considered as optimu m conditions. Improved rubbing fastness results for all the printed samples using the synthesized polyurethane acrylate binders in printed paste and UV cured are noticed as compared to those obtained by the traditional thermal cu ring technique. The results show that these binders can be used safely in preparing printing paste for printing cotton fabrics using pigment dyes.
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