葡萄糖-木质素基酚醛树脂:环保型低甲醛木材胶粘剂

Kaiyan Yang, Xiaowu Gong, Lanli Bai, Yun Zhang, Na Zhou
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摘要

目的制备低甲醛环保型葡萄糖-木质素基酚醛树脂。设计/方法/途径以尿素为甲醛吸附剂,直接用木质素代替甲醛制备木质素基酚醛树脂(LPF)。为了提高胶粘剂的性能,引入了生物基葡萄糖,得到了改性葡萄糖- lpf (GLPF)。结果表明:木质素对甲醛的替代量达到15 Wt。葡萄糖的加入提高了木材胶粘剂的性能,如所得GLPF的游离酚含量从5.60%降低到1.17%,降低了79.11%,GLPF的结合强度(1.19 MPa)比LPF提高了19.3%,GLPF的固化温度比LPF降低了13.08%。实际意义低甲醛环保型GLPF具有较高的粘接强度和较低的固化温度,有利于工业应用。制备的GLPF具有较低的游离甲醛和甲醛释放量,具有成本效益,有利于人体健康。木质素和葡萄糖的共同作用使木材胶粘剂的粘接强度提高,游离酚含量降低,固化温度降低。
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Glucose-lignin-based phenolic resin: an environmentally friendly low-formaldehyde wood adhesive
Purpose This study aims to prepare a low-formaldehyde and environmentally friendly glucose-lignin-based phenolic resin. Design/methodology/approach The authors directly used lignin to substitute formaldehyde to prepare lignin-based phenolic resin (LPF) with urea as formaldehyde absorbent. To improve the performance of the adhesive, the biobased glucose was introduced and the modified glucose-LPF (GLPF) was obtained. Findings The results showed that when the replacing amount of lignin to formaldehyde reached 15 Wt.%, the physical properties of the prepared LPF met the Chinese national standard, and the bonding strength increased by 21.9%, from 0.75 to 0.96 MPa, compared with PF. The addition of glucose boost the performance of wood adhesive, for example, the free phenol content of the obtained GLPF was significantly reduced by 79.11%, from 5.60% to 1.17%, the bonding strength (1.19 MPa) of GLPF increased by 19.3% in comparison to LPF and the curing temperature of GLPF decreased by 13.08%. Practical implications The low-formaldehyde and environmentally friendly GLPF has higher bonding strength and lower curing temperature, which is profitable to industrial application. Social implications The prepared GLPF has lower free formaldehyde and formaldehyde emission, which is cost-effective and beneficial to human health. Originality/value The joint work of lignin and glucose provides the wood adhesive with increased bonding strength, decreased free phenol content and reduced curing temperature.
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