三元金属配合物的合成、表征及应用研究

A. Faheim
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引用次数: 0

摘要

本章主要介绍了三元配合物的合成、表征及其应用。包括有一个或两个给体原子的共配体(二级配体)存在的三元配合物的合成。以吡啶酸、8-羟基喹啉、1,10-菲罗啉、二甲亚砜、三苯基膦和吡啶等氨基酸为代表的NN、NO、S、P和N给体,制备了三元配合物。这些三元配合物在DNA结合和裂解研究中的应用受到了广泛的关注。此外,本文还讨论了这些三元配合物作为酶抑制剂和催化某些反应的用途,从而揭示了这些配合物在各个领域的广泛应用。
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Study on Synthesis, Characterization and Applications of Ternary Metal Complexes
In this chapter, synthesis, characterization and applications of ternary complexes are reported. Synthesis of ternary complexes in presence of co-ligand (secondary ligand) with one or two donor atoms is included. Some amino acids, picolinic acid, 8-hydroxyquinoline, 1,10-phenanthroline, dimethylsulphoxide, triphenylphosphie and pyridine are used in preparation of the ternary complexes as  representative examples of NN, NO, S, P and N donor ligands. A considerable attention is paid to the application of these ternary complexes in DNA binding and cleavage study. Also, using these ternary complexes as inhibitor for enzyme and to catalyze some reactions is discussed to provide an insight of the wide applications of these complexes in various fields.
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