离子液体改性聚丙烯织物表面电阻率的研究

Y. Seki, Aylin Altınışık Tağaç
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引用次数: 0

摘要

以1-乙基-2,3-二甲基咪唑硫酸乙酯(EIL) (2,6,10 %w/v在乙醇中)和甲基三丁基硫酸甲铵(10,15,20 %w/v在乙醇中)两种不同浓度的离子液体对聚丙烯织物进行改性。改性前,用铬酸对织物进行预处理,使其表面活化。通过热重分析、表面电阻率测量和扫描电镜研究了改性的效果。预处理使表面电阻率从1010欧姆/平方提高到1013欧姆/平方。离子液体的改性使PP织物的表面电阻率在106 ~ 108欧姆/平方范围内短期和长期降低。提高离子液体的浓度是降低PP表面电阻率的有效途径,改性后的PP热稳定性发生改变。结果表明,经改性的聚丙烯织物表面和纱线间隙形成了一层涂层。这种环保的方法可以作为提高表面电阻率高的PP织物电导率的一种替代方法。
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AN INVESTIGATION ON SURFACE RESISTIVITY OF POLYPROPYLENEFABRICS MODIFIEDWITHIONICLIQUIDS
In this study, polypropylene fabric was modified with two types of ionic liquids such as 1- ethyl-2,3- dimethylimidazolium ethyl sulfate (EIL) (2, 6, 10 %w/v in ethanol) and methyl-trin-butylammonium methyl sulfate (10, 15, 20 %w/v in ethanol)at different concentrations. Before modification, the fabrics were pre- treated with chromic acid to activate the surface. The effect of the modifications was investigated by thermogravimetric analysis, surface resistivity measurements and scanning electron microscopy. The pre- treatment changed surface resistivity from 1010 to 1013 ohm/sq. The modifications with the ionic liquids decreased surface resistivity of the PP fabrics short and long-term periods in the range of 106 - 108 ohm/sq. Increasing the concentration of the ionic liquids can be considered as an efficient way to reduce the surface resistivity of PP. Thermal stability of the PP altered after modification. It was observed that a coating layer formed on surface of the fabric and in the gaps of the yarns of P P with modification. This environmentally- friendly method can be used as an alternative way for improving conductivity of PP fabrics generally characterized by their high surface resistivity.
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