伊朗真空渣油延迟焦化产率的预测

Farshad Torabi Esfahani, J. Ivakpour, M. Ehsani
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摘要

本文在实验结果的基础上,提出了延迟焦化产物产率随CCR和温度变化的关系式。为此,选择康拉德森碳渣(CCR)值在13.40-22.19 wt.%之间的伊朗真空渣油,在实验室间歇式常压延迟焦化反应器中,以10°C/min的升温速率加热,并在400-500°C的温度范围内热裂解2小时。在所有实验中都测量了馏出物(C5+-500℃)的量和焦炭收率,并根据每次实验中产物与原料之间的质量平衡计算了气(C1-C4)产物收率。根据所建立的函数,产品收率随CCR值线性变化,是温度的幂函数。进一步研究结果表明,CCR值每提高1 wt.%,馏出物产率降低约2.1 wt.%,但焦炭量和气产率分别提高1.2 wt.%和0.9 wt.%。
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Prediction of the Products Yield of Delayed Coking for Iranian Vacuum Residues
In this work, new correlations are proposed to predict the products yield of delayed coking as a function of CCR and temperature based on the experimental results. For this purpose, selected Iranian vacuum residues with Conradson carbon residue (CCR) values between 13.40-22.19 wt.% were heated at a 10 °C/min heating rate and thermally cracked in a temperature range of 400-500 °C in a laboratory batch atmospheric delayed coking reactor for 2 hours. The amount of distillate (C5+-500 °C) and coke yield were measured in all the experiments, and the gas (C1-C4) product yield was calculated based on mass balance between products and feedstock in each experiment. According to the developed functions, products yield changes with CCR value linearly and is a power function of temperature. The further investigation of the results show that by a 1 wt.% increase in CCR value, the distillate yield decreases by about 2.1 wt.%, but the amount of coke and gas yields rise by 1.2 wt.% and 0.9 wt.% respectively.
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