不同形貌ZnO薄膜的制备及其在染料敏化光伏电池中的应用

P. Sirimanne, E. Premalal
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引用次数: 2

摘要

采用电化学方法合成了不同形貌的ZnO薄膜。研究了ZnO薄膜的特性。在电解质中加入选定的前驱体可以改变ZnO薄膜的形貌,从而得到杂化的有机ZnO薄膜。从杂化ZnO - | - eosin薄膜中提取eosinY,得到了多孔ZnO薄膜。在染料敏化光伏电池中,采用不同的有机染料对ZnO薄膜进行敏化处理,作为光收集电极。研究了增敏氧化锌电极在I - | - i3 -氧化还原电解质中的光效应。在试验染料中,吲哚染料D149的性能较好。关键词:EosinY;杂化ZnO薄膜;D149染料DOI: http://dx.doi.org/10.4038/sljp.v12i0.4095斯里兰卡物理杂志,Vol. 12 (2011) 15-24
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Preparation of ZnO films with different morphologies and their applications in dye sensitized photo-voltaic cells
ZnO films with different morphologies were synthesized electrochemically. The characteristics of ZnO films were studied. Addition of selected precursors into the electrolyte changes the morphology of ZnO films and yields hybrid organic-ZnO films. Highly porous ZnO films were obtained by extracting eosin Y from hybrid ZnO|eosinY films. Different organic dyes were used to sensitize ZnO films by means of utilization as light harvesting electrodes in dye sensitized photovoltaic cells. Photo-effects of sensitized ZnO electrodes were studied in I - |I 3 - redox-electrolyte. Among tested dyes an indoline dye D149 produced better performance. Keywords: EosinY; Hybrid ZnO films; D149 dye DOI: http://dx.doi.org/10.4038/sljp.v12i0.4095 Sri Lankan Journal of Physics, Vol. 12 (2011) 15-24
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