明矾石矿石的快速分析方法

A. Ibrahimov, A. Heydarov, R. Vakilova, R.Y. Badalova
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引用次数: 0

摘要

本文介绍了用替代法测定明矾石矿石和工艺样品中明矾石含量的方法。该方法的实质是将矿石中的明矾矿物加热到完全分解的温度(800-8500C),以氧化铝和三氧化硫的量为基础,对矿石的矾化程度进行总质量损失。并与其它方法(热、化学、x射线相)进行了比较。该方法的优点是一次分析一个以上的样品,在短时间内完成分析,不做前期准备,也不使用化学试剂。明矾石矿石由明矾石和非明矾石(高岭石、赤铁矿、石英)组成。由于矿石在加热过程中的质量损失主要是由明矾石的分解引起的,因此,明矾石的质量损失与矿化程度之间存在a%=2.34ω损失的数学关系。对矿石中的氧化铝和三氧化硫,根据碳化程度可得ω(Al2O3)=0.8775⋅ω ω损耗,ω(SO3)=0.6888∙ω损耗。化学、微分分析方法实验证实了这些方程的充分性。确定了为了使矿石完全分解,需要在8500C下加热半小时,在8000C下加热一小时
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EXPRESS ANALYSIS METHOD OF ALUNITE ORE
The article presents a method to determine an amount of alunite in alunite ore and technological samples by alternative method. The essence of the method is that the alunite mineral in the ore is heated to the temperature of complete decomposition (800-8500C) and the degree of alunitation of the ore for the total mass loss, based on the amount of aluminum oxide and sulfur trioxide. The method was compared with other available methods (thermal, chemical, X-ray phase). The advantage of the method is that more than one sample is analyzed at a time, the analysis is completed in a short time, no preliminary preparations are made, nor chemical reagents are used. Alunite ore consists of alunite and non-alunite (kaolinite, hematite, quartz). Since the mass loss during the heating of the ore is mainly caused by the decomposition of alunite, a mathematical relationship of a%=2.34ωloss was found between the loss and the degree of alunitation. According to the degree of alunitation, for the aluminum oxide and sulfur trioxide in the ore, the expressions ω(Al2O3)=0.8775⋅ωloss, ω(SO3)=0.6888∙ωloss were obtained. Chemical, derivotographic methods of analysis experimentally confirmed the adequacy of these equations. It was established that in order to completely decompose the ore, it is necessary to heat it at 8500C for half an hour and at 8000C for an hour
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