镁辉石品种与铝同构取代成MFI和MEL沸石的再结晶

Gabriella Pál-Borbély , Hermann K. Beyer , Yoshimichi Kiyozumi , Fuijio Mizukami
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引用次数: 45

摘要

用铝及其铝硅酸衍生物同晶取代的镁硬石品种保留了镁硬石的骨架拓扑结构,通过四种TPA和TBA离子交换分别掺入到MFI型和mel型沸石中再结晶。分子筛的再结晶程度以及分子筛的大小和形状可以通过模板用量来控制。由于沸石组分的晶体尺寸小,部分再结晶产生的产物有望作为催化剂而有利地应用。
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Recrystallization of magadiite varieties isomorphically substituted with aluminum to MFI and MEL zeolites

Magadiite varieties isomorphically substituted with aluminum and their aluminosilicic acid derivatives retaining the framework topology of magadiite are recrystallized, after incorporation by ion exchange of four TPA and TBA ions, to MFI- and MEL-type zeolites, respectively. The recrystallization degree and the size and shape of the zeolite crystallites formed can be controlled by the amount of template applied. Partial recrystallization results in products which promise to be advantageously applicable as catalysts because of the small crystallite size of the zeolitic component.

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Author index Subject index Contents Investigation of organosilanes as structure-directing agents in zeolite synthesis The influence of gel properties on the kinetics of crystallization and particulate properties of MFI-type zeolities. I. The influence of time and temperature of gel ageing on the particulate properties of silicalite-1 microcrystals
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