能量色散掠入射x射线反射法在液/液和液/固界面结构分析中的应用

S. Sato, T. Imanaga, E. Matsubara, M. Saito, Y. Waseda
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引用次数: 4

摘要

证明了能量色散掠入射x射线反射法(ED-GIXR)表征液/液和液/固界面的有效性和实用性。该方法能够利用高能白光x射线辐射并获得更高的反射强度,从而减少了由于上半液体层吸收而导致的传统角色散方法的困难。介绍了一种专门用于ED-GIXR的新装置,并选择了一些溶液/汞和溶液/电极界面的x射线反射率曲线。
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Application of Energy Dispersive Grazing Incidence X-ray Reflectometry Method to Structural Analysis of Liquid/Liquid and Liquid/Solid Interfaces
The usefulness and validity of energy dispersive grazing incidence X-ray reflectometry (ED-GIXR) have been demonstrated for characterizing the liquid/liquid and liquid/solid interfaces. The present method appears to hold promise in reducing difficulty of conventional angular dispersive method due to absorption with an upper half liquid layer by enabling the use of high energy white X-ray radiation and obtaining much higher reflected intensity. An apparatus newly built for the exclusive use of the ED-GIXR is described with some selected examples of X-ray reflectivity profiles of solution/mercury and solution/electrode interfaces.
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