六亚甲基四胺-溴(HMTAB)一锅法合成四氰环丙烷衍生物

M. Heravi, H. Oskooie, Z. Latifi, Hoda Hamidi
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引用次数: 3

摘要

本文描述了在乙醇介质中催化量的DABCO存在下,以羰基化合物、丙二腈和六亚甲基四胺溴(HMTAB)为原料,在室温下直接合成四氰环丙烷的方法。
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One-Pot Synthesis of Tetracyanocyclopropane Derivatives Using Hexamethylenetetramine-Bromine (HMTAB)
Herein a direct method for synthesis of tetracyanocyclopropanes by the treatment of carbonyl compounds, malononitrile and hexamethylenetetramine-bromine (HMTAB) is described in the presence of catalytic amount of DABCO in ethanol media at room temperature.
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