改善椰壳颗粒聚丙烯复合材料的力学性能

H. C. Obasi, Uchechi C Mark, U. Mark
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引用次数: 6

摘要

传统无机填料广泛用于聚合物基复合材料的填料。然而,它们的加工困难和成本要求人们寻找可靠的有机替代品,如椰子壳填料。晒干的椰子壳经过燃烧、研磨和筛选,尺寸分别为63、150、300和425微米。以椰壳颗粒(CSP)为填料,采用注射熔融共混法制备了填料含量为0% ~ 40%的聚丙烯(PP)复合材料。研究了填料粒径对复合材料力学性能的影响。填料(CSP)的减小可使PP的屈服强度、抗拉强度、抗拉模量、抗弯强度、抗弯模量和硬度分别提高8.5 MPa、15.75 MPa、1.72 GPa、7.5 MPa、100 MPa和10.5 HR(63µm),提高幅度为40%。而PP复合材料的断裂伸长率和回弹模量随填料尺寸的增大而增大。扫描电镜分析表明,粒径为63µm的填料分布最佳,与PP基体的相互作用也更好。
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Improving the mechanical properties of polypropylene composites with coconut shell particles
Conventional inorganic fillers are widely used as fillers for polymer-based composites. Though, their processing difficulties and cost have demanded the quest for credible alternatives of organic origin like coconut shell fillers. Dried shells of coconut were burnt, ground, and sifted to sizes of 63, 150, 300, and 425 µm. The ground coconut shell particles (CSP) were used as a filler to prepare polypropylene (PP) composites at filler contents of 0% to 40% via injection melt blending process to produce PP composite sheets. The effect of the filler particle size on the mechanical properties was investigated. The decrease in the size of filler (CSP) was found to improve the yield strength, tensile strength, tensile modulus, flexural strength, flexural modulus, and hardness of PP by 8.5 MPa, 15.75 MPa, 1.72 GPa, 7.5 MPa, 100 MPa, and 10.5 HR for 63 µm at 40%, respectively. However, the elongation at break and modulus of resilience of the PP composites were seen to increase with increase in the filler size. Scanning electron microscope analysis showed that fillers with 63 µm particle size had the best distribution and interaction with the PP matrix resulting in enhanced properties.
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