纳米级零价铁颗粒和沸石还原水中硝酸盐的研究

Xu Chen, Tielong Li
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引用次数: 3

摘要

本研究探讨了利用实验室合成的纳米级零价铁(NZVI)还原硝酸盐。另一方面,研究了Fe - 0纳米颗粒与沸石复合对硝酸盐的反硝化作用。系统地研究了铁硝比和沸石的掺入对反应的影响。结果表明:浓度为80 mg/L的硝酸盐在60 min内大部分被去除,最终产物主要是含铁的氨,含铁的氨和沸石较少。纳米级铁在硝酸还原中的作用应参与两大过程:(a)直接参与氧化还原反应;(b)硝酸盐的吸附。沸石在硝酸还原中的作用仅为吸收氨。
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Reduction of Nitrate in Water by Nanoscale Zero-Valent Iron Particles and Zeolite
In this study, nitrate reduction using laboratory synthesized nanoscale zero-valent iron (NZVI) was discussed. On the other side, denitrification of nitrate with Fe 0 nanoparticles combined with zeolite was also investigated. The effects of iron-to-nitrate ratio and the affiliation of zeolite were studied systemically. The results show that nitrate with the concentration of 80 mg/L was mostly removed within 60 minutes, and the endproducts mainly are ammonia with Fe 0 but little ammonia with Fe 0 and zeolite. The role of nanoscale iron in the nitrate reduction should be take part in two major processes: (a) directly participate in the redox reaction; and (b) adsorption of nitrate. And the role of zeolite in nitrate reduction was only the absorption ammonia.
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