溶胶-凝胶法制备TiO2/沸石的结构和光催化性能

N. Aini, Fahmi Eksa Sagita, Khoridatud Diyanah, A. Arifah, S. N. Chasanah, A. Prasetyo
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引用次数: 0

摘要

将二氧化钛(TiO2)负载到天然沸石中,以提高其光催化活性。采用溶胶-凝胶法合成TiO2/沸石,组成比为5:95;10:90;20:80和30:70。x射线衍射测定了不同组成的TiO2/沸石具有锐钛矿和现代石相的特征。能谱表征表明TiO2/沸石中含有Ti元素,表明TiO2被成功负载到天然沸石中。随着TiO2含量的增加,红外和拉曼光谱的振动模式向更高的波数偏移,表明TiO2与沸石之间的分子相互作用导致了更高的能量振动。对亚甲基蓝降解的光催化活性测试表明,TiO2/沸石比TiO2和沸石本身具有更高的光催化活性。关键词:光催化剂,二氧化钛,沸石
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Structural and Photocatalytic Properties of TiO2/Zeolite Synthesized using Sol-Gel Method

Titanium dioxide (TiO2) is supported into natural zeolite to enhance its photocatalytic activity. TiO2/zeolite is synthesized using sol-gel method at composition ratio of 5:95; 10:90; 20:80 and 30:70%. Structural properties are measured by X-ray diffraction showed TiO2/zeolite in various composition has characteristic of anatase and modernite phase. The energy dispersive spectroscopy characterization shows TiO2/zeolite containing Ti element which indicates that TiO2is successfully supported into natural zeolite. Vibration mode of Infrared and Raman spectra tend shifted to higher wavenumber as increasing of TiO2 content indicating the higher energy vibration due to molecular interaction between TiO2 and zeolite. Photocatalytic activity test toward methylene blue degradation shows that TiO2/zeolite has higher activity than TiO2 and zeolite itself.

Keywords: Photocatalyst, titanium dioxide, zeolite

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