西阿布歇隆油田石油馏分的研究及合理利用

R. Hasanova, Yu.A. Abdullayeva, G. Mukhtarova, N. G. Alekperova, B. M. Aliyev, S. Aliyeva, S. B. Logmanova, N. F. Gafarova
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摘要

本文介绍了2014-2020年西部阿布歇隆油田原油的物理化学性质以及原油馏分质量的研究结果。研究表明,在物理化学性质方面,该油可与先前研究过的Darwin Kupesi和Pirallahi含油区的油相媲美。这种油350-500°C的油馏分具有低粘度指数和低倾点的特点。使用加氢裂化和选择性净化的组合工艺可以将粘度指数从0提高到~ 60单位,而仅使用选择性净化-从24提高到46单位。添加适当的添加剂后,可以获得VI高达105单位的15W/40型机油,这对应于“卢克标准”油的模拟。研究了从300 ~ 350℃的西部阿布歇隆石油馏分中提取脱芳油的工艺条件。对300-350℃的轻馏分进行深度脱芳,进行两级吸附纯化,芳烃含量≤3.0%。该馏分可作为生产白油、化妆品和药品的原料。同时计算了芳香烃、环烷烃、石蜡烃的比值(54.4/42.6/0.3),得到了与国外相同的经验公式C18.9H31.3。这些方法的缺点是目标馏分的逐步收率不够高(高达50%)。在加氢过程(加氢裂化、加氢异构化)存在的情况下,来自Western Absheron的石油馏分可以作为生产有价值产品的原料,包括白油和机油。
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Study of oil fractions from petroleum of the Western Absheron field for their rational use
The article presents the results of a studying the physical and chemical properties of oil from the Western Absheron field, as well as the quality of oil fractions of this oil for the period 2014-2020. It is shown that in terms of its physicochemical properties, this oil is comparable to the previously studied oils from the fields of the Darwin Kupesi and Pirallahi oil and gas bearing regions. The oil fractions of this oil 350-500°C are distinguished by a low viscosity index and a low pour point. The use of combined processes of hydrocracking and selective purification makes it possible to increase the viscosity index from 0 to ~ 60 units, while using only selective purification – from 24 to 46 units. After adding the appropriate additives, it is possible to obtain motor oils of the 15W/40 type with VI up to 105 units, which correspond to the analogue of “Lukoil-standard” oil. The conditions for obtaining dearomatized oils from the oil fraction of Western Absheron 300-350°C have been developed. For deep dearomatization of the light fraction 300-350°C, a two-stage adsorption purification was carried out to the content of aromatic hydrocarbons ≤3.0%. This fraction can be used as a raw material for the production of white oils, cosmetics and pharmaceuticals. At the same time, the ratios of aromatic, naphthenic, paraffinic hydrocarbons (54.4/42.6/0.3) were calculated and the empirical formula C18.9H31.3 was given, which corresponds to foreign counterparts. The disadvantage of these methods is the insufficiently high stepwise yield of the target fractions (up to 50%). In the presence of hydrogenation processes (hydrocracking, hydroisomerization), oil fractions of oil from Western Absheron can serve as raw materials for the production of valuable products – both white and motor oils.
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