γ辐照制备聚醋酸乙烯基CdS纳米纤维的球形组装体

Yi Xie , Zhengping Qiao , Meng Chen , Yingjie Zhu , Y.T. Qian
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引用次数: 11

摘要

首次采用γ射线辐照法制备了直径为120nm的10 × 50nm CdS纳米纤维球形组装体。在单点非均相体系中,氯化镉与二硫化碳发生辐照反应,单体醋酸乙烯酯发生聚合,在聚合物中形成球形半导体组件,得到结晶度良好的CdS纳米纤维。在常温常压下制备。
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Spherical assemblies of CdS nanofibers in poly(vinyl acetate) by γ-irradiation

γ-irradiation method was used for the first time to prepare spherical assemblies of 10 × 50nm CdS nanofibers in poly(vinyl acetate) with diameter of 120nm. The irradiation reaction between cadmium chloride and carbon disulfide, and the polymerization of monomer vinyl acetate occur in the one-spot heterogeneous system, leading to the formation of spherical assemblies of semiconductor in polymer and the resulting CdS nanofibers with a good crystallinity. The preparation was done at room temperature and ambient pressure.

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