研究了不完全燃烧产物在吸附-催化-化学吸附体系中的转化机理

D. K. Musaeva, M. Eshmuhamedov
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摘要

本文讨论了不完全燃烧产物在驱动氧化物碱、碱土、两性金属和铁、锰等具有充分连接价的金属上催化转化和化学吸附的可能性,使不完全燃烧产物在气流剥离时形成连接金属。确定在过程中,金属在吸附-催化体系中形成化学吸附。研究了不完全燃烧产物在含铁、含锰等氧化物(碱性、碱土、两性金属和连接价金属)上的氧化机理。物理化学和光谱分析表明,在不完全燃烧离子Mn4+的吸收过程中,Mn3+和Fe3+移动到最底部的价态并形成盐。结果表明,易多孔金属氧化物与锰混合后产生的不完全燃烧产物产生的清工业气体,同时以有机结合的方式使金属保持在金属中
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THE MECHANISM OF THE CONVERSIONS OF THE PRODUCTS OF THE INCOMPLETE COMBUSTION ON POLIMETALL ADSORBTIONKATALISIS- CHEMOSORBCION SYSTEM
In article is considered possibility of the catalytic conversion and chemosorption of the products of the incomplete combustion on actuated oxides alkaline, alkaline earth and amphoteric metal and metal with connecting valence sufficient as iron and manganese, bring about forming the join metal at peelings of the gas flow from products of the incomplete combustion. It is determined that in process chemosorption is formed join metal, which is accumulated in time sorption-catalytic system. The studied mechanism of the oxidation of the products of the incomplete combustion on oxides alkaline, alkaline earth, amphoteric metal and metal with connecting valence, as iron and manganese containing systems. Physics-chemical and spectral analysis is installed that, at xemosorbtion of the products of the incomplete combustion ion Mn4+, Mn3+ and Fe3+ moves over to undermost valence of the condition and form to salts. It is revealed that clear industrial gas surge from products of the incomplete combustion on easy porous have eaten metallic oxides with manganese by concoction is accompanied simultaneous increase being kept in him metal in the manner of metal of the organic join
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