功能化氧化石墨烯和碳纳米管合成含活性纳米结构填料的纳米复合材料的新方法

ECSOC-25 Pub Date : 2021-11-13 DOI:10.3390/ecsoc-25-11679
L. Jadhav, R. Patil, Nikhil Borane, S. Mishra, G. Yadav, D. Patil, V. Patil
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引用次数: 1

摘要

利用功能化石墨烯和碳纳米管的化学反应性,开发了一种新的合成方法,碳纳米管是化学上不同的氧化石墨烯/碳纳米管和甲苯二异氰酸酯的共价组合。从而产生协同聚合物纳米复合材料。综合复合材料同时具有共价和π - π相互作用,分别在D和G波段1345和1590 cm−1处的拉曼吸收光谱证实了氧化石墨烯和MWCNTs的sp2杂化框架。通过超声引发的经典固化反应得到甲苯二异氰酸酯和氧化石墨烯/氟碳纳米管激发聚合物配方。该方法允许50 wt.%的氧化石墨烯/FCNT掺杂而不产生偏析,确保了与法律钢表面的良好附着力。氧化石墨烯和FCNT的大表面积和形貌特征保证了分子的稳定性和分散性。与高温危险固化反应相比,它的优点是克服了石墨烯脱落的问题,并且不允许碳纳米管在较高浓度下在束内滑动而脱落。
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A Novel Synthetic Approach of Functionalised GO and CNT to Nanocomposite Containing Active Nanostructured Fillers for Classical Isocyanate Curing
: A novel synthetic method has been developed by utilizing the chemical reactivity of functionalized graphene and CNT with a covalent combination of chemically diverse GO/FCNT and toluene diisocyanate. Thereby yield a synergistic polymer nanocomposite. Comprehensive composite material has simultaneous covalent as well as π - π interactions confirms sp2-hybridized frameworks of graphene oxide and MWCNTs by Raman absorption spectra at 1345 and 1590 cm −1 of D and G band respectively. Toluene diisocyanate and GO/FCNT inspired polymeric formulation obtained by the classical curing reaction initiated by ultrasound sonication. This method allowed 50 wt.% doping of GO/FCNT without segregation ensures good adhesion to the law steel surface. Large surface area and morphological character of GO and FCNT by SEM and TEM ensure stable and dispersed integrated molecules. It has advantages over the high-temperature hazardous curing reaction overcomes the problem of graphene exfoliation and does not allow CNT slipping within the bundle to falls apart at higher concentration.
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