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引用次数: 0

摘要

新出现的污染物(EPs)被认为是全球监测的挑战,它们在环境中的浓度非常低,适当的采样和分析方法仍在开发中。许多已发表的考虑EPs鉴定的研究类型仅依赖于分析方法和更有效的更高数量的EPs。水中优先EPs的定量测定需要在水、水悬浮物、土壤和生物群中应用先进的超灵敏仪器技术。水质参数的监管框架通常不包括微塑料、EPs及其代谢物;特别是地下水水质的监测与控制迫在眉睫,但尚未实现。水中的EPs来源是污水、工业和农业废弃物,据联合国估计,每年产生的废水约为1500公里,约为世界上所有河流现有水量的6倍。2015年,在经济快速增长的中国,水是一种稀缺资源,仅占世界淡水总量的8%,却无法满足占世界22%人口的用水需求。此外,MIP对TC有选择性识别,并促进了TC在含有TC、土霉素(Oxy)和环丙沙星(CIP)的三元溶液中的光降解。TC、Oxy和CIP的选择性降解系数分别为1.67和1.25。质谱(MS)分析了TC的光降解机理,表明TC是逐步分解产生co2、h2o等气体的。
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EPs Antibiotics: Photodecomposition and Biocarbon Adsorption
The emerging pollutants (EPs) are considered a global monitoring challenge, present in the environment in very reduced concentrations, and the proper methods for sampling and analysis are still in development. Many published types of research considering the EPs identification only depend on the analytical methodology and a more efficient higher number of EPs. The quantitative determination of the prioritized EPs in water needs advanced and ultra-sensitive instrumental techniques applied in water, water-suspended matter, soil, and biota. The regulatory framework of the water-quality parameters does not often include the microplastics, EPs, and their metabolites; especially, the ground-water water-quality monitoring and control are urgent but not yet achieved. The EPs sources in water are the sewage, industrial, and agricultural waste discard, and the UN estimated that the wastewater produced annually is about 1500 km 3 , about six times more water than existing in all rivers of the word. In 2015, in China, which has a fast-growing economy, the water is a scarce resource with just 8% of the world’s fresh water to meet the water needs of the 22% of the world’s population. Also, MIP showed the TC-selective recognition and promoted the photodegradation of TC in the ternary solutions containing TC, oxytetracycline (Oxy), and ciprofloxacin (CIP). The coefficients of selectivity of degradation from TC, Oxy, and CIP were 1.67 and 1.25, respectively. The photodegradation mechanism of TC ana-lyzed by mass spectrum (MS) indicated the TC decomposition step by step, resulting in CO 2 , H 2 O, and other gases.
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