电热雾化-腔衰荡光谱(ETA-CRDS)初步结果

C. Winstead, F. Mazzotti, J. Mierzwa, G. P. Miller
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引用次数: 15

摘要

本文首次报道了电热雾化-腔衰荡光谱用于痕量元素分析的实验结果。采用石墨炉腔衰荡光谱对铅水溶液进行了分析,获得了峰高吸收测量的初步检出限约为1 pg。未使用化学基质改性剂。这些初步结果和理论检出限的估计表明,ETA和CRDS的耦合有可能成为一种有价值的分析原子光谱新技术。
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Preliminary results for electrothermal atomization-cavity ringdown spectroscopy (ETA-CRDS)
We report the first experimental results using electrothermal atomization-cavity ringdown spectroscopy for trace elemental analysis. Lead aqueous standard solutions were analyzed using graphite furnace-cavity ringdown spectroscopy and a preliminary detection limit of approximately 1 pg was obtained for peak height absorption measurements. No chemical matrix modifiers were used. These preliminary results together with an estimate of theoretical detection limits suggest that the coupling of ETA and CRDS has the potential to become a valuable new technique in analytical atomic spectrometry.
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