{"title":"Mössbauer有机锡化合物的光谱和结构。四极分裂与分子间缔合的关系","authors":"A. Maddock, R. H. Platt","doi":"10.1039/J19710001191","DOIUrl":null,"url":null,"abstract":"The Mossbauer spectra of cyclohexyltin derivatives and of the compounds Ph2Sn(X)·[CH2]4·Sn(X)Ph2(X = I, OH, O·CO·Me, or Ph), BunSn(O·CO·Me)4–n(n= 2 or 3), and Bu2Sn maleate have been recorded. These data are used to define the range of quadrupole splittings associated with tetrahedral organotin compounds. It is shown that the simple point-charge model does not account for the quadrupole splittings of compounds with differing co-ordination numbers. Quadrupole splitting data are used empirically to discuss intermolecular association in organotin compounds.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"16","resultStr":"{\"title\":\"Mössbauer spectra and structures of organotin compounds. The relationship between quadrupole splitting and intermolecular association\",\"authors\":\"A. Maddock, R. H. Platt\",\"doi\":\"10.1039/J19710001191\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The Mossbauer spectra of cyclohexyltin derivatives and of the compounds Ph2Sn(X)·[CH2]4·Sn(X)Ph2(X = I, OH, O·CO·Me, or Ph), BunSn(O·CO·Me)4–n(n= 2 or 3), and Bu2Sn maleate have been recorded. These data are used to define the range of quadrupole splittings associated with tetrahedral organotin compounds. It is shown that the simple point-charge model does not account for the quadrupole splittings of compounds with differing co-ordination numbers. Quadrupole splitting data are used empirically to discuss intermolecular association in organotin compounds.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"16\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710001191\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710001191","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mössbauer spectra and structures of organotin compounds. The relationship between quadrupole splitting and intermolecular association
The Mossbauer spectra of cyclohexyltin derivatives and of the compounds Ph2Sn(X)·[CH2]4·Sn(X)Ph2(X = I, OH, O·CO·Me, or Ph), BunSn(O·CO·Me)4–n(n= 2 or 3), and Bu2Sn maleate have been recorded. These data are used to define the range of quadrupole splittings associated with tetrahedral organotin compounds. It is shown that the simple point-charge model does not account for the quadrupole splittings of compounds with differing co-ordination numbers. Quadrupole splitting data are used empirically to discuss intermolecular association in organotin compounds.