掺钙铝合金AlMg5.5Li2.1Zr0.15在NaCl电解质介质中的阳极行为

I. Ganiev, F. Saidova, S. U. Khudoyberdizoda, Salima S. Savdulloeva, J. H. Jayloev, Vladimir D. Abulhaev
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引用次数: 0

摘要

硬铝合金广泛应用于航空工业、高速列车(例如新干线列车)的生产和许多其他机械工程领域(因为它比纯铝耐用得多)。除了高操作性能外,硬铝的多种用途是由于其高技术效率,这为通过所有已知的铸造和塑料加工方法获得产品创造了先决条件。硬铝属于结构合金的范畴,其特点是强度增加。它们是由铝制成的。不同比例的铜、锰和镁被用作添加剂。硬铝的性能取决于热处理和合金元素的添加量。本文介绍了钙对硬铝型铝合金АlМg5.5Li2.1Zr0.15在NaCl电解质介质中阳极行为影响的研究结果。采用恒电位法,在电位扫描速率为2 mV⋅s ^(-1)的动电位模式下,研究了合金的腐蚀电化学行为。结果表明,钙添加剂可使初始合金АlМg5.5Li2.1Zr0.15的阳极腐蚀速率降低8-10%。结果发现,氯离子浓度的增加有助于阳极腐蚀速率的增加,而不管合金中的钙含量如何АlМg5.5Li2.1Zr0.15。
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ANODIC BEHAVIOR OF ALUMINUM ALLOY AlMg5.5Li2.1Zr0.15 DOPED WITH CALCIUM IN THE ELECTROLYTE MEDIUM OF NaCl
Duralumin alloy is widely used in the aircraft industry, in the production of high-speed trains (for example, Shinkansen trains) and in many other branches of mechanical engineering (since it is significantly more durable than pure aluminum). Along with high operational properties, the diverse use of duralumin is due to its high technological efficiency, which creates prerequisites for obtaining products by all known methods of casting and plastic processing. Duralumin belongs to the category of structural alloys, which are characterized by increased strength. They are based on aluminum. Copper, manganese, and magnesium are used as additives in different percentages. The properties of duralumin depend on the heat treatment and the amount of alloying elements added. The article presents the results of a study of the effect of calcium on the anodic behavior of aluminum alloy АlМg5.5Li2.1Zr0.15 of the duralumin type in the medium of the NaCl electrolyte. The study of the corrosion−electrochemical behavior of alloys was carried out by a potentiostatic method in a potentiodynamic mode with a potential sweep rate of 2 mV ⋅ s ^(-1). It is shown that calcium additives reduce the rate of anodic corrosion of the initial alloy АlМg5.5Li2.1Zr0.15 by 8-10%. It was found that an increase in the concentration of chloride ions contributes to an increase in the rate of anodic corrosion regardless of the calcium content in the alloy АlМg5.5Li2.1Zr0.15.
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