以玻璃渣和转炉炉渣为原料制备多孔玻璃晶材料

Y. Koltsova
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摘要

本研究的目的是制备一种以玻璃渣和转炉炉渣为原料的多孔玻璃晶材料,并将其作为成气添加剂。在这项工作中,分析了所研究的炉渣的化学和物相组成,并对其样品进行了差热分析。转炉炉渣以2.5% ~ 30%的质量分数加入到生产质量中,其余为玻璃碎料。在850 ~ 925℃的温度范围内,对试样进行Вurning测试,对研究试样采用体积计进行体积测定,计算膨胀系数,确定抗压强度,并对孔隙平均直径对结构类型的影响进行分析。建立了所研究材料的膨胀系数与配料成分和燃烧温度的关系。为获得膨胀系数为2.16-2.67,细孔结构均匀(主要孔径小于0.5 mm)的多孔材料,在质量组成中加入10-15 wt%的转炉炉渣,推荐的燃烧温度范围为850-900℃。对所得材料的相组成分析表明,硅灰石是主要的晶相,由于晶体的针状结构,具有增强作用,有助于提高强度特性。所研制的多孔玻璃晶材料可作为轻质混凝土的保温材料和集料材料。
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PRODUCTION OF POROUS GLASS-CRYSTALLINE MATERIALS BASED ON GLASS CULLET AND CONVERTER SLAG
The study conducted the research aimed to obtaining a porous glass-crystalline materials based on glass cullet and converter slag, which was used as a gas-forming additive. In this work, the chemical and phase compositions of the studied slag were analyzed, and a differential thermal analysis of its sample was carried out. Converter slag was added to the composition of the masses in an amount of 2.5 to 30 wt%, the rest was glass cullet. Вurning of the samples was carried out in the temperature range of 850-925 ° C. For the samples under study, using a sand volumetric meter, the volume was determined and the swelling coefficient was calculated, the compressive strength was determined, and the type of structure, which depends on the average diameter of the prevailing pores, was analyzed. The dependence of the swelling coefficient of the investigated materials on the burdening composition and burning temperature has been established. To obtain porous materials with a swelling coefficient of 2.16-2.67 and uniform fine-porous structure (predominant pore size less than 0.5 mm), it is optimal to introduce converter slag into the composition of the masses in an amount of 10-15 wt%, and the recommended temperature range their burning 850-900 ° C. Analysis of the phase composition of the materials obtained indicates the presence of wollastonite as the main crystalline phase, which, due to the acicular structure of the crystals, has a reinforcing effect and contributes to an increase in strength characteristics. The developed porous glass-crystalline materials can be used as thermal insulation and aggregates in lightweight concrete.
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