{"title":"Ni (II)和Cu (II)离子配体N2O2半大环的合成及光谱研究","authors":"Sameena Rasheed, A. Dwivedi, M. U. Khan","doi":"10.20431/2349-0403.0503003","DOIUrl":null,"url":null,"abstract":"The new series of demi-macrocycles of the type [C14 H30 N2 O2 (Cl2 O4) 2] having N2O2 as donors ligand were synthesized by the equimolar condensation reaction of ethane-1, 2-diamine in acetone in presenced of perchloric acid. The head unit of demi-macrocycle formed was proposed by the two acetone molecules [M (C14H30N2O2) (ClO4)2] Where, M = Ni(II) and Cu(II) were formed by the reaction of proposed demi-macrocycle with respective metal salts. The complexes formed were characterized by the elemental analysis, conductance and magnetic susceptibilities measurements, and also by spectral methods.","PeriodicalId":13721,"journal":{"name":"International Journal of Advanced Research in Chemical Science","volume":"17 1","pages":"15-19"},"PeriodicalIF":0.0000,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, and Spectral Studies of Demi-macrocycles of Ligand N2O2 with Ni (II) and Cu (II) Ions\",\"authors\":\"Sameena Rasheed, A. Dwivedi, M. U. Khan\",\"doi\":\"10.20431/2349-0403.0503003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The new series of demi-macrocycles of the type [C14 H30 N2 O2 (Cl2 O4) 2] having N2O2 as donors ligand were synthesized by the equimolar condensation reaction of ethane-1, 2-diamine in acetone in presenced of perchloric acid. The head unit of demi-macrocycle formed was proposed by the two acetone molecules [M (C14H30N2O2) (ClO4)2] Where, M = Ni(II) and Cu(II) were formed by the reaction of proposed demi-macrocycle with respective metal salts. The complexes formed were characterized by the elemental analysis, conductance and magnetic susceptibilities measurements, and also by spectral methods.\",\"PeriodicalId\":13721,\"journal\":{\"name\":\"International Journal of Advanced Research in Chemical Science\",\"volume\":\"17 1\",\"pages\":\"15-19\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Advanced Research in Chemical Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.20431/2349-0403.0503003\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Advanced Research in Chemical Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.20431/2349-0403.0503003","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis, and Spectral Studies of Demi-macrocycles of Ligand N2O2 with Ni (II) and Cu (II) Ions
The new series of demi-macrocycles of the type [C14 H30 N2 O2 (Cl2 O4) 2] having N2O2 as donors ligand were synthesized by the equimolar condensation reaction of ethane-1, 2-diamine in acetone in presenced of perchloric acid. The head unit of demi-macrocycle formed was proposed by the two acetone molecules [M (C14H30N2O2) (ClO4)2] Where, M = Ni(II) and Cu(II) were formed by the reaction of proposed demi-macrocycle with respective metal salts. The complexes formed were characterized by the elemental analysis, conductance and magnetic susceptibilities measurements, and also by spectral methods.
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