{"title":"新型乙烯金配合物[ph3pac (CF3)]的晶体结构","authors":"C. Gilmore, P. Woodward","doi":"10.1039/C29710001233","DOIUrl":null,"url":null,"abstract":"Structure determination by X-ray diffraction shows that the compound (Ph3P)2Au2C2(CF3)2 is cis-1,2-bis(triphenylphosphinegold)-1,2-bis(trifluoromethyl)-ethylene, the first ethylenic compound in which both carbon atoms are σ-bonded to the metal atom of an organometallic ligand.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"129 1","pages":"1233-1234"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"12","resultStr":"{\"title\":\"Crystal structure of a new ethylenic gold complex, [Ph3PAuC(CF3)]2\",\"authors\":\"C. Gilmore, P. Woodward\",\"doi\":\"10.1039/C29710001233\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Structure determination by X-ray diffraction shows that the compound (Ph3P)2Au2C2(CF3)2 is cis-1,2-bis(triphenylphosphinegold)-1,2-bis(trifluoromethyl)-ethylene, the first ethylenic compound in which both carbon atoms are σ-bonded to the metal atom of an organometallic ligand.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"129 1\",\"pages\":\"1233-1234\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001233\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001233","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal structure of a new ethylenic gold complex, [Ph3PAuC(CF3)]2
Structure determination by X-ray diffraction shows that the compound (Ph3P)2Au2C2(CF3)2 is cis-1,2-bis(triphenylphosphinegold)-1,2-bis(trifluoromethyl)-ethylene, the first ethylenic compound in which both carbon atoms are σ-bonded to the metal atom of an organometallic ligand.
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