改性萃取冶金废分散相作为橡胶基材料功能填料

IF 1.4 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Elastomers and Plastics Pub Date : 2010-05-01 DOI:10.1177/0095244310362404
N. Dishovsky, D. Grigorova, V. Iliev, S. Borrós
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引用次数: 0

摘要

在过去的十年中,我们目睹了用于家庭、工业和军事目的的电磁场源的数量和种类的空前增长。近年来,随着人类健康和生活、工作质量的提高,对超高频电磁辐射的防护变得越来越重要。除了生产吸收剂的种类之外,开发新的、更有效的、更便宜的吸收材料的问题也成为人们感兴趣的问题。有效吸收超高频电磁辐射的橡胶基复合材料中主要使用的功能填料是羰基铁或磁铁矿,在相同情况下与石墨或炭黑结合使用。同时,在有色金属冶炼的烧结厂,经过气体净化设备(静电除尘器(ESP))后,每年产生的废粉高达几千吨。x射线衍射分析表明,粉末中主要含有磁铁矿。本文以废烧结粉为基料,研究了一种碳改性填料。制备了不同浓度改性填料和未改性填料的橡胶基复合材料。对所制备的橡胶基复合材料的硫化性能、物理力学性能、电学性能和微波性能进行了测试和评价。结果表明,改性填料的使用改善了材料的微波特性、强度变形性能和老化稳定性。
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Modified Waste Dispersion Phase from the Extraction Metallurgy as Functional Filler for Rubber-based Materials
In the past decade, we have witnessed unprecedented increase in the quantities and variety of the electromagnetic field sources used for domestic, industrial, and military purposes. Of late, the protection from the ultra high frequency (UHF) electromagnetic radiation is gaining importance owing to human health care and quality of life and work improvement. Independently from the variety of produced absorbers, the problem with development of new, more effective, and cheap absorbing materials becomes a question of interest. The mainly used functional fillers in rubber-based composites effectively absorbing UHF electromagnetic radiations are carbonyl iron or magnetite, in same cases in combination with graphite or carbon black. At the same time in sinter plants of the extraction ferrous metallurgy, after gas cleaning equipment (electrostatic precipitators (ESP)) up to thousand tons of waste powder have been generated annually. The X-ray diffraction analysis shows that powder contains mainly magnetite. In the present research on the base of waste sinter powder a filler modified with carbon was obtained. The rubber-based composites with different concentration of modified and nonmodified fillers were produced. The vulcanization, physico-mechanical, electrical, and microwave properties of the obtained rubber-based composites were measured and evaluated. The results show that the modified fillers usage improves microwave characteristics, strength-deformation properties, and aging stability.
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来源期刊
Journal of Elastomers and Plastics
Journal of Elastomers and Plastics 工程技术-材料科学:综合
CiteScore
3.30
自引率
5.90%
发文量
41
审稿时长
6 months
期刊介绍: The Journal of Elastomers and Plastics is a high quality peer-reviewed journal which publishes original research on the development and marketing of elastomers and plastics and the area in between where the characteristics of both extremes are apparent. The journal covers: advances in chemistry, processing, properties and applications; new information on thermoplastic elastomers, reinforced elastomers, natural rubbers, blends and alloys, and fillers and additives.
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