三甲基膦与溴乙酸乙酯合成的磷盐铜(II)配合物的立体合成与鉴定

A. Naghipour, Abozar Bastami, A. Ezati
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引用次数: 0

摘要

磷盐具有通式,由亚离子磷四面体衍生而来,如碘化磷。一般来说,磷是一种有机衍生物,如四苯基氯化磷和四甲基碘化磷。本课题制备并鉴定了含磷化合物[c2h5coo (ch2pph 3br)]及其铜(II)配合物[c2h5coo (ch2pph 3br)] [cu2cl6]。以溴乙酸乙酯和terphenylphosphine为原料,制备了几种不同种类的磷。然后利用磷化合物与Na 2 [Cu 2 Cl 6]的反应制备最终化合物。然后,利用光谱学方法对这些化合物的制备进行了研究。
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Synthesis and identification of copper (II) complexes using phosphonium salt resulting from the combination of trinylphosphine and ethyl bromoacetate, using stereoscopic methods
Phosphonium salts have the general formula  and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl  phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C 2 H 5 COO (CH 2 PPh 3 Br)] and its copper (II) complex [C 2 H 5 COO (CH 2 PP 3 Br)] [Cu 2 Cl 6 ] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na 2 [Cu 2 Cl 6 ]. Then, using spectroscopic methods, preparation of these compounds was investigated.
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