研究合成和可生物降解聚合物的性能,着眼于它们在食品工业中应用的可能性

O. Ershova, E. Mullina, J. A. Bessonova, K. V. Bagreeva
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引用次数: 0

摘要

本文论述了食品工业中包装材料环境友好的实际问题。这项工作的目的是研究生物可降解和合成聚合物的物理和机械特性,目的是更新用更环保的材料替代合成包装材料。本文讨论了新型聚乳酸基生物降解材料的主要特点。对生物可降解材料和合成高分子材料的强度和吸附性能进行了比较分析。根据吸水率、抗穿刺性、变形强度和热物理特性等参数对所研究材料进行了对比分析。本文还介绍了所分析的高分子材料吸水性能的研究结果。给出了试验结果,为建立熔体法制备聚乳酸的温度-时间参数提供了可能。用DSC法对聚合物在热裂解过程中发生的弛豫和相变进行了分析。在实验过程中,对国产聚乳酸(PLA)可生物降解材料的化学性能进行了实验研究。分析了合成高分子材料和天然高分子材料的主要优缺点。此外,本文还对所研究的高分子材料在实际应用中的环境问题进行了分析。结论是关于在食品工业的各个分支中使用所提出的材料的可能性和安全性。根据实验结果,合成高分子材料在所研究的物理和机械参数方面略高于生物高分子材料,然而,考虑到环境友好性和在自然条件下完全利用的可能性,这一事实并不会降低生物高分子材料在食品工业中使用的相关性。此外,对聚乳酸(PLA)生物聚合物的化学成分分析表明,通过引入改性增强剂和疏水性添加剂,可以抵消样品强度参数的下降。
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Investigation of the properties of synthetic and biodegradable polymers, with a view to the possibility of their use in the food industry
The article deals with the actual problem of environmental friendliness of packaging materials used in the food industry. The aim of the work was to study the physical and mechanical characteristics of biodegradable and synthetic polymers, with the aim of updating the replacement of synthetic packaging materials with more environmentally friendly materials. The article discusses the main characteristics of innovative biodegradable materials based on polylactides (PLA). A comparative analysis of the strength and sorption properties of both biodegradable and synthetic polymeric materials is presented. A comparative analysis of the materials under study was carried out according to the following parameters: water absorption, puncture resistance, deformation-strength and thermophysical characteristics. The paper also presents the results of a study of the water-absorbing capacity of the analyzed polymeric materials. The results of tests are presented, which make it possible to establish the temperature-time parameters of the processing of polylactide by the melt method. The data obtained by the DSC method on the establishment of relaxation and phase transitions that occur in the polymer during thermolysis are analyzed. During the experiment, experimental studies of the chemical properties of biodegradable materials based on polylactides (PLA), made in China were carried out. The main advantages and disadvantages of synthetic and natural polymeric materials are considered. In addition, the paper analyzes the environmental aspects of the practical application of the studied polymeric materials. Conclusions are formulated about the possibility and safety of using the presented materials in various branches of the food industry. Based on the results of the experiment, it was found that synthetic polymer materials slightly exceed biopolymer materials in terms of the investigated physical and mechanical parameters, however, given the environmental friendliness and the possibility of complete utilization in natural conditions, this fact does not reduce the relevance of using biopolymers in the food industry. In addition, the analysis of data on the chemical composition of the studied biopolymers based on polylactides (PLA) showed that the decrease in the strength parameters of the presented samples can be neutralized by introducing modifying strengthening and hydrophobizing additives.
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