{"title":"用链裂反应法和无水马来酸接枝改性天然橡胶Sir-20","authors":"A. Sinaga, Eddyanto Eddyanto, Andreas Nababan","doi":"10.24114/ijcst.v5i2.37451","DOIUrl":null,"url":null,"abstract":"In this research, natural rubber SIR-20 was modified by the chain severing reaction method with the addition of decimal peroxide and flowing oxygen gas as much as 2 l/mint for 6 hours at a temperature of 135oC while stirring. Fourier Transformed-Infra Red (FTIR) spectra obtained, it can be concluded that there has been a chain breaking reaction seen from the functional group analysis which produces a series of distinctive peaks in the hydroxyl group (OH) and 2 carbonyl peaks (C=O) which are obtained at natural rubber SIR-20 + 3 phr DCP of 3435 and 1715, respectively; 1737 and has a strong intensity which indicates a chain breaking reaction has occurred in natural rubber SIR-20. From the results of the FTIR analysis, it was found that the C=O group was getting sharper which was the typical absorption peak originating from maleic anhydride grafted on the natural rubber chain.","PeriodicalId":13519,"journal":{"name":"Indonesian Journal of Chemical Science and Technology (IJCST)","volume":"3 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Modified Natural Rubber Sir-20 Using Chain Scission Reaction Method And Grafting With Anhydrous Maleic\",\"authors\":\"A. Sinaga, Eddyanto Eddyanto, Andreas Nababan\",\"doi\":\"10.24114/ijcst.v5i2.37451\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this research, natural rubber SIR-20 was modified by the chain severing reaction method with the addition of decimal peroxide and flowing oxygen gas as much as 2 l/mint for 6 hours at a temperature of 135oC while stirring. Fourier Transformed-Infra Red (FTIR) spectra obtained, it can be concluded that there has been a chain breaking reaction seen from the functional group analysis which produces a series of distinctive peaks in the hydroxyl group (OH) and 2 carbonyl peaks (C=O) which are obtained at natural rubber SIR-20 + 3 phr DCP of 3435 and 1715, respectively; 1737 and has a strong intensity which indicates a chain breaking reaction has occurred in natural rubber SIR-20. From the results of the FTIR analysis, it was found that the C=O group was getting sharper which was the typical absorption peak originating from maleic anhydride grafted on the natural rubber chain.\",\"PeriodicalId\":13519,\"journal\":{\"name\":\"Indonesian Journal of Chemical Science and Technology (IJCST)\",\"volume\":\"3 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-08-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Indonesian Journal of Chemical Science and Technology (IJCST)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.24114/ijcst.v5i2.37451\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Indonesian Journal of Chemical Science and Technology (IJCST)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.24114/ijcst.v5i2.37451","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Modified Natural Rubber Sir-20 Using Chain Scission Reaction Method And Grafting With Anhydrous Maleic
In this research, natural rubber SIR-20 was modified by the chain severing reaction method with the addition of decimal peroxide and flowing oxygen gas as much as 2 l/mint for 6 hours at a temperature of 135oC while stirring. Fourier Transformed-Infra Red (FTIR) spectra obtained, it can be concluded that there has been a chain breaking reaction seen from the functional group analysis which produces a series of distinctive peaks in the hydroxyl group (OH) and 2 carbonyl peaks (C=O) which are obtained at natural rubber SIR-20 + 3 phr DCP of 3435 and 1715, respectively; 1737 and has a strong intensity which indicates a chain breaking reaction has occurred in natural rubber SIR-20. From the results of the FTIR analysis, it was found that the C=O group was getting sharper which was the typical absorption peak originating from maleic anhydride grafted on the natural rubber chain.