高速薄膜混合器制备纳米粒子分散体的光学性质

Tadahito Takahashi, H. Miyamoto, Takahiro Kono, Hiroki Gonome, J. Yamada, Akihito Shundo
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引用次数: 3

摘要

直径在亚微米范围内的超细颗粒由于具有良好的光学性能,如透明度和紫外线防护性,经常被用作化妆品材料。然而,这些粒子具有比传统颜料更高的界面能;因此,它们有相互作用形成二次集聚的趋势,这可能会导致这些功能的恶化。为了解决这些问题,利用高速混合器施加大剪切力是产生单分散均匀分散的超细颗粒的有前途的方法之一。在本研究中,利用高速薄膜混合器研究了光学性质与高速混合的关系。当亲水性tio2纳米粒子分散在离子交换水中时,消光系数随转子周边转速的增加而减小。粒径分布取决于混合速度,并与区分系数的增大有良好的相关性。
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The Optical Properties of Nanoparticle Dispersions Prepared by a High Speed Thin Film Mixer
Ultrafine particles having diameters in the submicron region have often been used as cosmetic materials because they have excellent optical properties, such as transparency and UV light protection. However, these particles have interfacial energy higher than conventional pigments; thus, they have a tendency to interact with each other to form a secondary agglomeration which may cause deterioration of those functions. To solve these problems, applying high shear force using a high-speed mixer is one of the prospective methods to produce monodispersed uniform dispersion of ultrafine particles. In this study, the relationship between optical properties and high-speed mixing was examined using a high speed thin film mixer. When hydrophilic TiO 2 nanoparticles were dispersed in ion-exchanged water, the extinction coefficient decreased in accordance with the peripheral speed of the rotor. Particle size distribution depends on the mixing speed and has good correlation with the increase of distinction coefficient.
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