在离子液体催化剂的存在下合成双二苯甲酸酯、双对二氯二苯甲酸酯乙二醇醚

P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva
{"title":"在离子液体催化剂的存在下合成双二苯甲酸酯、双对二氯二苯甲酸酯乙二醇醚","authors":"P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva","doi":"10.37474/0365-8554/2022-9-55-59","DOIUrl":null,"url":null,"abstract":"Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.","PeriodicalId":8668,"journal":{"name":"Azerbaijan Oil Industry","volume":"13 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The synthesis of bis-dibenzoat, bis-p-dichloro-dibenzoat ethers of ethylene-glycol in the presence of ionic-liquid catalyst\",\"authors\":\"P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva\",\"doi\":\"10.37474/0365-8554/2022-9-55-59\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.\",\"PeriodicalId\":8668,\"journal\":{\"name\":\"Azerbaijan Oil Industry\",\"volume\":\"13 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-09-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Azerbaijan Oil Industry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.37474/0365-8554/2022-9-55-59\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Azerbaijan Oil Industry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37474/0365-8554/2022-9-55-59","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

以苯甲酸、对氯苯甲酸和乙二醇为原料,以2:1、2的比例,在110 оС温度下,在n-甲基吡拉酮-氢硫酸盐离子液体催化剂存在下,反应时间为6-7小时,合成了双二苯甲酸酯和双对二氯二苯甲酸乙二醇醚,相应的收率为82 - 92%。确定了合成的化合物醚的理化参数,并对其结构进行了光谱鉴定。对合成的复合醚进行了柴油热氧化稳定性试验。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
The synthesis of bis-dibenzoat, bis-p-dichloro-dibenzoat ethers of ethylene-glycol in the presence of ionic-liquid catalyst
Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Increasing performance efficiency of reconstructed oil fields Research of the lithofacies properties of the Productive series rocks in the north-west flank Bulla-Project field Study of the influence of non-carbon gases on the condensate recovery coefficient of gas condensate fields using a hydrodynamic model Investigation into restoration of waterflooding process in the Darvin bankasi field Formation products from the n-undecane oxidation reaction
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1