库克尔赛特页岩半焦化气催化合成噻吩的研究

D.Yu. Zhogin , A.M. Myasoyedov , G.Ye. Voropanov , M.A. Ryashentseva
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引用次数: 0

摘要

采用铝-铬-镧-氧化镧催化剂,以库克尔赛特页岩半焦化气为原料,经杂环化反应制备了含噻吩的液体催化剂。催化产物中噻吩的浓度是工业副产物焦化噻吩精矿的1.5 ~ 2倍。同时,半焦化气的硫化氢含量从9-12%降低到0.5 vol.%或更低。
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Catalytic synthesis of thiophene from the gas formed in the semicoking of kukersite shale

Liquid catalyzate containing thiophene has been obtained from the gas formed in semicoking of kukersite shale by means of heterocyclization over an alumina-chromium-lanthanum lanthanum oxide catalyst. The thiophene concentration in the catalyzate is 1.5–2 times higher than in industrial byproduct coking thiophene concentrate. At the same a reduction in the hydrogen sulphide content of the semicoking gas from 9–12% to 0·5 vol.% or less has been obtained.

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