游离脂肪酸的气相色谱分析。第1部分。原则和方法变体

J. Pörschmann, T. Welsch, S. Pörschmann
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引用次数: 3

摘要

从文献检索出发,总结了当今气相色谱仪在分析游离脂肪酸时所面临的问题。在柱技术方面,自制的OV-1/FFAP混相毛细管柱适合对这些极性分子进行充分的无尾洗脱。具有两个或两个以上碳原子的脂肪酸可以在酸性毛细管柱上以欠活化状态进行分析,而涉及甲酸和二羧酸细胞的失活程序。
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Gas chromatographic analysis of free fatty acids. Part 1. Principles and methodic variants
Proceeding from a literature search the problems faced by the today's gas chromatographer concerned with analysis of free fatty acids are summarized. In terms of column technology self-made OV-1/FFAP mixed phase capillary columns are well suited for adequate tailing — free elution of these polar molecules. Whereas fatty acids having two and more carbon atoms can be analyzed in an underivatized state on acidic capillary columns, the involving of formic acid and dicarboxylic acids cells for deactivation procedures.
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