作为轻质高强材料基础的粉煤灰微球窄组分特性研究

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY Journal of Siberian Federal University. Chemistry Pub Date : 2019-06-01 DOI:10.17516/1998-2836-0123
E. S. Rogovenko, O. A. Kushnerova, E. Fomenko
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引用次数: 1

摘要

从煤粉燃烧得到的飞灰和局部精选飞灰的空心球精矿中分离出粒径为−0.4 + 0.2 mm、容重较低的微球窄组分,容重范围为0.34 ~ 0.64 g/cm3。所得窄馏分的主要化学成分为SiO2 - 55-66和Al2O3 - 21-40 wt. %。部分非晶玻璃相为63 ~ 93,莫来石相为1 ~ 34,石英相为2 ~ 8,方解石相为0 ~ 1 wt %。结果表明,微球的容重最大值为0.64 g/cm3,外壳表观厚度为20 μm,具有最佳的强度性能。选择连续两次增加强度的压缩加载,颗粒的容重和表观壳厚分别增加到0.86 g/cm3和29 μm。结果表明,单环结构的球体主要受到破坏;具有网状和固体结构的颗粒改善了微球窄组分的强度特性
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Characteristics of the Narrow Fractions of Fly Ash Microspheres as the Basis of Light-Weight High-Strength Materials
The narrow fractions of microspheres with a size of −0.4 + 0.2 mm with a low bulk density in the range of 0.34–0.64 g/cm3 were separated from cenosphere concentrates of fly ashes and fly ash from local selection obtained from pulverized coal combustion. The main components of the chemical composition in obtained narrow fractions are SiO2 – 55–66 and Al2O3 – 21–40 wt. %. The part of amorphous glass phase are 63–93, the mullite phase are 1–34, the quartz phase are 2–8 and the calcite phase are 0–1 wt. %. It is found that microspheres, characterized by maximum values of bulk density 0.64 g/cm3 and apparent thickness of the shell 20 μm, has the best strength properties. The successive twofold compressive loading the particles by increased strength were selected, for which the values of bulk density and apparent shell thickness increased to 0.86 g/cm3 and 29 μm, respectively. It is shown that the spheres with the single-ring structure are primarily subjected to destruction; the particles with network and solid structure provide improved strength characteristics of narrow fractions of microspheres
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