nichtebenen处境deformationsschwingungν2相对国情咨文totalsymmetrischen valenzsehwingungν1在trithiocarbonaten

A. Müller, B. Krebs
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引用次数: 5

摘要

观测到三硫代碳酸盐中CS32−离子ν1(A1 ')和νt2(E ')振动的频率比,根据晶体场,可能也取决于金属与硫之间的键相互作用,可以假设低于或高于1的值。
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Die lage der nichtebenen deformationsschwingung ν2 relativ zur lage der totalsymmetrischen valenzsehwingung ν1 in trithiocarbonaten

The frequency ratio of the ν1(A1′) and νt2(E′) vibrations of the CS32− ion in trithiocarbonates was observed to assume values below as well as above unity, depending on the crystal field and, probably, on bond interactions between metal and sulfur.

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